Dibromido[(tert-butylamino)dimethyl(piperidin-1-ylmethyl)silane-κ2 N,N′]zinc(II)
نویسندگان
چکیده
The title compound, [ZnBr(2)(C(12)H(28)N(2)Si)], is an example of a neutral coordination compound of a bidentate ligand to a metal centre with the Zn atom being coordinated by two Br and two N atoms, yielding a slightly distorted tetra-hedral coordination environment.
منابع مشابه
Dibromido{2-[(4-fluorophenyl)iminomethyl]pyridine-κ2 N,N′}zinc
In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49 (1)°. In the crystal, weak C-H⋯F and C-H⋯Br hydrogen bonds are observed.
متن کاملPoly[[μ2-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ2 N 3:N 3′](μ2-terephthalato-κ2 O 1:O 4)zinc(II)]
In the title coordination polymer, [Zn(C(8)H(4)O(4))(C(14)H(14)N(4))](n), the Zn(II) atom is coordinated by two N atoms from two 1,2-bis-(imidazol-1-ylmeth-yl)benzene ligands as well as by the two O atoms from two terephthalate ligands, confering a tetra-hedral coordination geometry. The bridging ligands generate a three-dimensional structure.
متن کاملBis[μ2-1,2-bis(imidazol-1-ylmethyl)benzene-κ2 N 3:N 3′]bis[dichloridozinc(II)]
In the crystal structure of the centrosymmetric title compound, [Zn(2)Cl(4)(C(14)H(14)N(4))(2)], the Zn(II) atom is coordinated by two N atoms from two 1,2-bis-(imidazol-1-ylmeth-yl)benzene ligands and two Cl atoms to confer a distorted tetra-hedral geometry at the metal center.
متن کاملDibromido(6,6′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc(II)
In the title compound, [ZnBr(2)(C(12)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral arrangement by an N,N'-bidentate 6,6'-dimethyl-2,2'-bipyridine ligand and two bromide ions. In the crystal, there are aromatic π-π contacts between the pyridine rings [centroid-centroid distances = 3.818 (3) and 3.728 (4) Å].
متن کاملDibromido{2-[(4-bromophenyl)iminomethyl]pyridine-κ2 N,N′}zinc(II)
In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04 (17)°.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009